全文获取类型
收费全文 | 74097篇 |
免费 | 7728篇 |
国内免费 | 4416篇 |
专业分类
电工技术 | 6072篇 |
技术理论 | 3篇 |
综合类 | 5903篇 |
化学工业 | 10712篇 |
金属工艺 | 4390篇 |
机械仪表 | 5013篇 |
建筑科学 | 6159篇 |
矿业工程 | 1952篇 |
能源动力 | 2199篇 |
轻工业 | 5376篇 |
水利工程 | 1662篇 |
石油天然气 | 3448篇 |
武器工业 | 768篇 |
无线电 | 9421篇 |
一般工业技术 | 8384篇 |
冶金工业 | 2711篇 |
原子能技术 | 914篇 |
自动化技术 | 11154篇 |
出版年
2024年 | 186篇 |
2023年 | 1211篇 |
2022年 | 2218篇 |
2021年 | 3353篇 |
2020年 | 2494篇 |
2019年 | 1964篇 |
2018年 | 2066篇 |
2017年 | 2364篇 |
2016年 | 2218篇 |
2015年 | 3125篇 |
2014年 | 3946篇 |
2013年 | 4662篇 |
2012年 | 5462篇 |
2011年 | 5794篇 |
2010年 | 5171篇 |
2009年 | 5045篇 |
2008年 | 5131篇 |
2007年 | 4596篇 |
2006年 | 4449篇 |
2005年 | 3625篇 |
2004年 | 2553篇 |
2003年 | 2206篇 |
2002年 | 2451篇 |
2001年 | 2159篇 |
2000年 | 1658篇 |
1999年 | 1371篇 |
1998年 | 972篇 |
1997年 | 788篇 |
1996年 | 678篇 |
1995年 | 529篇 |
1994年 | 438篇 |
1993年 | 302篇 |
1992年 | 265篇 |
1991年 | 188篇 |
1990年 | 139篇 |
1989年 | 113篇 |
1988年 | 83篇 |
1987年 | 51篇 |
1986年 | 42篇 |
1985年 | 25篇 |
1984年 | 24篇 |
1983年 | 14篇 |
1982年 | 31篇 |
1981年 | 19篇 |
1980年 | 22篇 |
1979年 | 11篇 |
1977年 | 4篇 |
1976年 | 6篇 |
1959年 | 5篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
22.
Wenfei Tian Yi Zheng Weiqun Wang Donghai Wang Michael Tilley Guorong Zhang Zhonghu He Yonghui Li 《Comprehensive Reviews in Food Science and Food Safety》2022,21(3):2274-2308
The health benefits of whole wheat consumption can be partially attributed to wheat's phytochemicals, including phenolic acids, flavonoids, alkylresorcinols, carotenoids, phytosterols, tocopherols, and tocotrienols. It is of increasing interest to produce whole wheat products that are rich in bioactive phytochemicals. This review provides the fundamentals of the chemistry, extraction, and occurrence of wheat phytochemicals and includes critical discussion of several long-lasting issues: (1) the commonly used nomenclature on distribution of wheat phenolic acids, namely, soluble-free, soluble-conjugated, and insoluble-bound phenolic acids; (2) different extraction protocols for wheat phytochemicals; and (3) the chemistry and application of in vitro antioxidant assays. This review further discusses recent advances on the effects of genotypes, environments, field management, and processing techniques including ultrafine grinding, germination, fermentation, enzymatic treatments, thermal treatments, and food processing. These results need to be interpreted with care due to varied sample preparation protocols and limitations of in vitro assays. The bioaccessibility, bioavailability, metabolism, and potential health benefits of wheat phytochemicals are also reviewed. This comprehensive and critical review will benefit scientific researchers in the field of bioactive compounds of cereal grains and also those in the cereal food industry to produce high-quality functional foods. 相似文献
23.
Here, highly‐oriented poly(m‐phenylene isophthalamide)/polyacrylonitrile multi‐walled carbon nanotube (PMIA/PAN‐MWCNT) composite nanofiber membranes with excellent mechanical strength and thermal stability are successfully produced using electrospinning. It is demonstrated that the cooperation of multi‐walled carbon nanotubes (MWCNT) and high‐speed rotating collection is beneficial to the acquisition of highly oriented fibers and effectively improves the mechanical strength of the membrane along the orientation direction. Specifically, the tensile stress of poly(m‐phenylene isophthalamide)/polyacrylonitrile (PMIA/PAN) membrane is enhanced significantly from 10.6 to 20.7 MPa, benefiting from the highly oriented alignment of the fibers as well as the reinforcing effect of MWCNTs on the fibers. Furthermore, the stressing process of single fiber and fiber aggregates is carefully simulated, and the influence of MWCNTs on the mechanical properties of PMIA/PAN‐MWCNT membranes is analyzed comprehensively, providing a meaningful auxiliary means for the study of mechanical properties. In addition, the composite nanofiber membrane has the advantages of both PMIA and PAN, possessing high temperature resistance, flame‐retardancy, and chemical stability, for an ideal high‐temperature material. In short, the as‐prepared PMIA/PAN‐MWCNT composite membrane with excellent comprehensive property emerges a promising application in many fields, especially in high‐tech. 相似文献
24.
For the defect that the mechanical properties of polypyrrole supercapacitors decrease with charge and discharge cycles, and
the cycle stability is poor, a compound method of polypyrrole electrode for supercapacitors based on multi-walled carbon nanotubes
is proposed. The structure of the formed polypyrrole coated multi-walled carbon nanotubes effectively increase the specific surface
area of the electrode material, the utilization rate of the active material and the electrical conductivity, improve the rapid charge and
discharge performance of the electrode material, and greatly improve cyclic stability of polypyrrole. The composite electrode materi-
al of polypyrrole and functionalized multi-walled carbon nanotubes for supercapacitors is prepared by pulse current deposition meth-
od. It is scanned at a scanning rate of 1000mV?s -1 in a 3mol?L -1 potassium chloride electrolyte, after 100,000-cycle, the capacity on-
ly declines by 16%. 相似文献
25.
A broadband double‐layer transmissive metasurface (TMS) for effective generate vortex electromagnetic wave is presented in this paper. The proposed TMS consists of two types of elements. The first element is composed of a multi‐resonant dipole and four metal vias. The metal vias increase the coupling strength between the upper and lower layers to improve transmission efficiency. On the basis of the first element, the second element adds stubs to ensure sufficient phase shift. The far‐field cross polarisation is eliminated by special element arrangement. Then, a centre‐fed linear polarisation TMS is designed to generate orbital angular momentum beams with mode l = ? 1. The proposed TMS is designed, manufactured and measured to verify the proposed design. The measured results indicate that a maximum gain of 20.8 dBi and narrow divergence angle of ±5° are achieved at 18 GHz. Furthermore, mode purity is higher than 86.1% within the 17 to 19 GHz band. The proposed double‐layer TMS saved costs, reduced weight and without assembly error is a good candidate for OAM generator. 相似文献
26.
In the water distribution network (WDN), although the water demand of the node is changing constantly, the water quantity and water pressure of the node need to be met at each moment. To realize energy saving and consumption reduction, it is proposed to control the nodal water head of WDN in an appropriate narrow range. The frequent large fluctuation of the water demand, which may lead the water pressure exceed the expected range, increases the difficulty of the zone control. To realize optimized WND control, a novel zone predictive control is proposed, where two switching cases are considered. The switching condition is whether there are feasible solutions to keep the pressure within the expected region over the prediction horizon. When the condition is satisfied, the controller minimizes the variation of inputs with constraints of pressure range for ensuring the tank level staying within the expected zone and obtaining optimal economic cost. When the current pressure is out of the expected region or the condition is not satisfied due to the large variation of water demand, a reference trajectory of outputs is introduced, which is combined with the inputs as an optimization variable, and the constraints of expected zone are moved from the output to the introduced reference trajectory. Through minimizing the distance between reference trajectory and output, the controller will keep the tank level from deviating too far from the expected zone and will drive the tank level rapidly into the expected zone once the tank level exceeds the expected range. An application of the proposed zone MPC to WDN in Shinan District of Shanghai is given to illustrate its effectiveness. 相似文献
27.
28.
Xian Suo Xili Cui Lifeng Yang Nan Xu Yuqi Huang Yi He Sheng Dai Huabin Xing 《Advanced materials (Deerfield Beach, Fla.)》2020,32(29):1907601
The design of highly stable and efficient porous materials is essential for developing breakthrough hydrocarbon separation methods based on physisorption to replace currently used energy-intensive distillation/absorption technologies. Efforts to develop advanced porous materials such as zeolites, coordination frameworks, and organic polymers have met with limited success. Here, a new class of ionic ultramicroporous polymers (IUPs) with high-density inorganic anions and narrowly distributed ultramicroporosity is reported, which are synthesized by a facile free-radical polymerization using branched and amphiphilic ionic compounds as reactive monomers. A covalent and ionic dual-crosslinking strategy is proposed to manipulate the pore structure of amorphous polymers at the ultramicroporous scale. The IUPs exhibit exceptional selectivity (286.1–474.4) for separating acetylene from ethylene along with high thermal and water stability, collaboratively demonstrated by gas adsorption isotherms and experimental breakthrough curves. Modeling studies unveil the specific binding sites for acetylene capture as well as the interconnected ultramicroporosity for size sieving. The porosity-engineering protocol used in this work can also be extended to the design of other ultramicroporous materials for the challenging separation of other key gas constituents. 相似文献
29.
为适应当前全球对放射性诊断核素99m Tc需求量不断增长的需要,阿尔及利亚比林核研究中心对多用途重水反应堆(Multi-purposes Heavy Water Research Reactor,MHWRR)实施升级改造,提出建立不停堆连续辐照生产裂变钼的能力需求。在对裂变钼靶件堆内辐照堆芯物理计算分析、热工水力计算分析、靶件出堆过程热工计算分析以及裂变99Mo产额计算等分析研究的基础上,结合反应堆设施原有限制条件,创新地提出了采用短时间临时停堆方式的技术方案,既能实现阿方产量目标,又能满足辐照安全要求。方案得到了阿方认可,工程实施后的初步调试结果表明:理论计算值与实验值符合较好,在无参考可借鉴实例的情况下,提出的辐照技术方案和工艺流程是合理可行的。 相似文献
30.